Selective oxidation in vitro by myeloperoxidase of the N-terminal amine in apolipoprotein B-100

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Selective oxidation in vitro by myeloperoxidase of the N-terminal amine in apolipoprotein B-100.

In contrast to the multiple low abundance 2,4-dinitrophenylhydrazine-reactive tryptic peptides formed by oxidation of LDL with reagent HOCl in vitro, myeloperoxidase-catalyzed oxidation produces a dominant product in considerably greater yield and selectivity. This modified peptide had a single amino-terminal sequence corresponding to amino acids 53-66 of apolipoprotein B-100 (apoB-100), but it...

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ژورنال

عنوان ژورنال: Journal of Lipid Research

سال: 2001

ISSN: 0022-2275

DOI: 10.1016/s0022-2275(20)31515-7